M. K. Mishra and Y. Yagci, Handbook of Vinyl Polymers: Radical Polymerization, Process, and Technology: Second Edition, CRC Press2016

A. Witkowski, A. A. Stec, and T. R. Hull, The influence of metal hydroxide fire retardants and nanoclay on the thermal decomposition of EVA, Polym. Degrad. Stab, vol.97, issue.11, pp.2231-2240, 2012.

L. P. Dong, C. Deng, R. M. Li, Z. J. Cao, L. Lin et al., Poly(piperazinyl phosphamide): A novel highlyefficient charring agent for an EVA/APP intumescent flame retardant system, RSC Advances, vol.6, issue.36, pp.30436-30444, 2016.

C. Feng, M. Liang, J. Jiang, H. Liu, and J. Huang, Synergistic effect of ammonium polyphosphate and triazine-based charring agent on the flame retardancy and combustion behavior of ethylene-vinyl acetate copolymer, J. Anal. Appl. Pyrolysis, vol.119, pp.259-269, 2016.

T. Giang, D. Hoang, and J. Kim, Effect of intumescent compositions on flammable properties of ethylene vinyl acetate and polypropylene, Fire Mater, vol.41, issue.7, pp.857-863, 2017.

J. Alongi, Z. Han, and S. Bourbigot, Intumescence: Tradition versus novelty. A comprehensive review, Prog. Polym. Sci, vol.51, pp.28-73, 2015.

S. Duquesne, R. Delobel, M. L. Bras, and G. Camino, A comparative study of the mechanism of action of ammonium polyphosphate and expandable graphite in polyurethane, Polym. Degrad. Stab, vol.77, issue.2, pp.333-344, 2002.

Y. Lu, Y. Zhang, and W. Xu, Flame retardancy and mechanical properties of ethylene-vinyl acetate rubber with expandable graphite/ammonium polyphosphate/dipentaerythritol system, J. Macromol. Sci., Part B: Phys, vol.50, issue.10, pp.1864-1872, 2011.

C. Guo, L. Zhou, and J. Lv, Effects of expandable graphite and modified ammonium polyphosphate on the flameretardant and mechanical properties of wood flour-polypropylene composites, Polymers and Polymer Composites, vol.21, issue.7, pp.449-456, 2013.

W. W. Focke, H. Badenhorst, W. Mhike, H. J. Kruger, and D. Lombaard, Characterization of commercial expandable graphite fire retardants, Thermochim. Acta, vol.584, pp.8-16, 2014.

M. Jimenez, S. Duquesne, and S. Bourbigot, Characterization of the performance of an intumescent fire protective coating, Surf. Coat. Technol, vol.201, issue.3-4, pp.979-987, 2006.

M. Bugajny, S. Bourbigot, M. L. Bras, and R. Delobel, The origin and nature of flame retardance in ethylene-vinyl acetate copolymers containing hostaflam AP 750, Polym. Int, vol.48, issue.4, pp.264-270, 1999.

F. J. Gotor, M. Macías, A. Ortega, and J. M. Criado, Simultaneous use of isothermal, nonisothermal, and constant rate thermal analysis (CRTA) for discerning the kinetics of the thermal dissociation of smithsonite, Int. J. Chem. Kinet, vol.30, issue.9, pp.647-655, 1998.

S. P. Ribeiro, L. D. Cescon, R. Q. Ribeiro, A. Landesmann, L. R. Estevão et al., Effect of clay minerals structure on the polymer flame retardancy intumescent process, Appl. Clay Sci, vol.161, pp.301-309, 2018.

N. Hansupo, G. Tricot, S. Bellayer, P. Roussel, F. Samyn et al., Getting a better insight into the chemistry of decomposition of complex flame retarded formulation: New insights using solid state NMR, Polym. Degrad. Stab, vol.153, pp.145-154, 2018.
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S. Pappalardo, P. Russo, D. Acierno, S. Rabe, and B. Schartel, The synergistic effect of organically modified sepiolite in intumescent flame retardant polypropylene, Eur. Polym. J, vol.76, pp.196-207, 2016.

C. Gérard, G. Fontaine, S. Bellayer, and S. Bourbigot, Reaction to fire of an intumescent epoxy resin: Protection mechanisms and synergy, Polym. Degrad. Stab, vol.97, issue.8, pp.1366-1386, 2012.

A. Karrasch, E. Wawrzyn, B. Schartel, and C. Jäger, Solid-state NMR on thermal and fire residues of bisphenol A polycarbonate/silicone acrylate rubber/bisphenol A bis(diphenyl-phosphate)/(PC/ SiR/BDP) and PC/SiR/BDP/zinc borate (PC/SiR/BDP/ZnB) -Part I: PC charring and the impact of BDP and ZnB, Polym. Degrad. Stab, vol.95, issue.12, pp.2525-2533, 2010.

A. Karrasch, E. Wawrzyn, B. Schartel, and C. Jäger, Solid-state NMR on thermal and fire residues of bisphenol A polycarbonate/silicone acrylate rubber/bisphenol A Bis(diphenyl-phosphate) (PC/SiR/BDP) and PC/SiR/BDP/zinc borate (PC/SiR/BDP/ZnB) -Part II: The influence of SiR, Polym. Degrad. Stab, vol.95, issue.12, pp.2534-2540, 2010.

N. Pécoul, S. Bourbigot, and B. , Revel, 13C, 25Mg and 11B solid-state NMR study of a fire retarded ethylene-vinyl acetate copolymer, Macromol. Symp, vol.119, pp.309-315, 1997.

G. C. Stael and M. I. Tavares, NMR carbon-13 high resolution study of poly(ethylene-co-vinyl acetate), Polym. Test, vol.16, issue.2, pp.193-198, 1997.

M. Delfini, A. L. Segre, and F. Conti, Sequence Distributions in Ethylene-Vinyl Acetate Copolymers. I.13C Nuclear Magnetic Resonance Studies, Macromolecules, vol.6, issue.3, pp.456-459, 1973.

S. Bourbigot, M. L. Bras, and R. Delobel, Carbonization mechanisms resulting from intumescence association with the ammonium polyphosphate-pentaerythritol fire retardant system, Carbon, vol.31, issue.8, pp.1219-1230, 1993.

S. Bourbigot, M. L. Bras, R. Delobel, and J. M. Trémillon, Synergistic effect of zeolite in an intumescence process: Study of the interactions between the polymer and the additives, Journal of the Chemical Society -Faraday Transactions, vol.92, issue.18, pp.3435-3444, 1996.

F. Samyn, S. Bourbigot, S. Duquesne, and R. Delobel, Effect of zinc borate on the thermal degradation of ammonium polyphosphate, Thermochim. Acta, vol.456, issue.2, pp.134-144, 2007.

C. Mercier, L. Montagne, H. Sfihi, G. Palavit, J. C. Boivin et al., Local structure of zinc ultraphosphate glasses containing large amount of hydroxyl groups: 31P and 1H solid state nuclear magnetic resonance investigation, J. Non-Cryst. Solids, vol.224, issue.2, pp.163-172, 1998.

A. Sut, S. Greiser, C. Jäger, and B. Schartel, Synergy in flame-retarded epoxy resin: Identification of chemical interactions by solid-state NMR, J. Therm. Anal. Calorim, vol.128, issue.1, pp.141-153, 2017.

S. Bourbigot, M. L. Bras, R. Delobel, R. Decressain, and J. P. Amoureux, Synergistic effect of zeolite in an intumescence process: Study of the carbonaceous structures using solid-state NMR, Journal of the Chemical SocietyFaraday Transactions, vol.92, issue.1, pp.149-158, 1996.