I. Friedman and W. D. Long, Volcanic glasses, their origins and alteration processes, vol.67, pp.127-133, 1984.

A. Verney-carron, S. Gin, and G. Libourel, A fractured roman glass block altered for 1800 years in 829 seawater: Analogy with nuclear waste glass in a deep geological repository. Geochimica et 830 Cosmochimica Acta, vol.72, pp.5372-5385, 2008.

. Andra-collectif, Dossier d'options de sûreté -Partie après fermeture (DOS-AF), ANDRA. p, pp.832-833, 2016.

C. Poinssot and S. Gin, Long-term Behavior Science: The cornerstone approach for reliably 834 assessing the long-term performance of nuclear waste, Journal of Nuclear Materials, vol.835, issue.420, pp.182-192, 2012.

T. De-echave, Influence of iron on the alteration of the SON68 nuclear glass in the Callovo-837 Oxfordian groundwater, Applied Geochemistry, vol.100, pp.268-278, 2019.

T. De-echave, Effect of clayey groundwater on the dissolution rate of SON68 simulated 839 nuclear waste glass at 70 °C, Journal of Nuclear Materials, vol.503, pp.279-289, 2018.

T. Suzuki-muresan, Alteration of vitrified intermediate level nuclear waste in alkaline 841 media: effects of cementitious materials, pH and temperature, vol.8, pp.842-37665, 2018.

P. C. Rieke, Adaptation of the GRAAL model of Glass Reactivity to accommodate non-linear 844 diffusivity, Journal of Nuclear Materials, vol.512, pp.79-93, 2018.

P. Frugier, Modeling glass corrosion with GRAAL. npj Materials Degradation, vol.2, p.10, 2018.

T. Ducasse, Alteration of synthetic basaltic glass in silica saturated conditions: Analogy 848 with nuclear glass, Applied Geochemistry, vol.97, p.11, 2018.

S. Gin, Atom-Probe Tomography, TEM and ToF-SIMS study of borosilicate glass alteration 850 rim: A multiscale approach to investigating rate-limiting mechanisms. Geochimica et 851 Cosmochimica Acta, vol.202, p.12, 2017.

M. Collin, Structure of International Simple Glass and properties of passivating layer 853 formed in circumneutral pH conditions. npj Materials Degradation, vol.2, p.13, 2018.

B. Grambow and R. Muller, First-order dissolution rate law and the role of surface layers in glass 855 performance assessment, Journal of Nuclear Materials, vol.298, issue.2, p.14, 2001.

R. Hellmann, Nanometre-scale evidence for interfacial dissolution-reprecipitation control 857 of silicate glass corrosion, Nature Materials, 2015, vol.14, issue.3, p.15

T. Geisler, Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion 859 mechanism, Journal of Non-Crystalline Solids, vol.356, p.16, 2010.

W. L. Ebert, R. F. Hoburg, J. K. Bates-;-gong, and W. L. , Secondary phase formation and the microstructural evolution of surface layers 863 during vapor phase alteration of the French SON68 nuclear waste glass at 200°C, in Scientific 864 Basis for Nuclear Waste Management XIX, vol.32, pp.133-137, 1991.

. Res, P. A. Soc-;-philadephia, and U. , , vol.866, pp.197-204

J. K. Bates, M. G. Seitz, and M. J. Steindler, The relevance of vapor phase hydration aging to 867 nuclear waste isolation. Nuclear and Chemical Waste Management, vol.5, p.19, 1984.

J. K. Bates, Issues affecting the prediction of glass reactivity in an unsaturated 869 environment, Journal of Nuclear Materials, vol.190, pp.198-227, 1992.

J. K. Bates, The hydration alteration of a commercial nuclear waste glass. Chemical 871 Geology, vol.51, pp.79-87, 1985.

T. Abrajano, J. K. Bates, and C. D. Byers, Aqueous corrosion of natural and nuclear waste glasses I

, Comparative rates of hydration in liquid and vapor environments at elevated temperatures, Journal of Non Crystalline Solids, vol.874, p.22, 1986.

T. A. Abrajano, J. K. Jr, J. J. Bates, and W. L. Mazer-;-gong, Analytical electron microscopy study of surface layers formed on the French 879 SON68 nuclear waste glass during vapor hydration at 200°C, Journal of Nuclear Materials, vol.108, issue.2, p.24, 1989.

E. M. Pierce, The Accelerated Weathering of a Radioactive Low-Activity Waste Glass Under 882

, Hydraulically Unsaturated Conditions: Experimental Results from a Pressurized Unsaturated Flow 883 Test, vol.155, p.25, 2006.

D. A. Mckeown, Tc and Re Behavior in Borosilicate Waste Glass Vapor Hydration Tests. 885 Environmental Science & Technology, vol.41, p.26, 2007.

A. C. Buechele, Tc and Re behavior in borosilicate waste glass vapor hydration tests II, Journal of nuclear materials, vol.887, issue.1-3, p.27, 2012.

N. J. Cassingham, Alteration layer formation of Ca-and Zn-oxide bearing alkali borosilicate 889 glasses for immobilisation of UK high level waste: A vapour hydration study, Journal of Nuclear, vol.890, pp.639-646, 2016.

J. Neeway, Vapor hydration of SON68 glass from 90 °C to 200 °C: A kinetic study and 892 corrosion products investigation, Journal of Non Crystalline Solids, vol.358, issue.21, p.29, 2012.

A. Chaou, Vapor hydration of a simulated borosilicate nuclear waste glass in unsaturated 894 conditions at 50 °C and 90 °C. RSCC Advances, 2015.

A. Chaou, The role of pH in the vapor hydration at 175 °C of the French SON68 glass. 896 Applied Geochemistry, vol.76, p.31, 2017.

R. Bouakkaz, A. Abdelouas, and B. Grambow, Kinetic study and structural evolution of SON68 898 nuclear waste glass altered from 35 to 125 °C under unsaturated H 2 O and D 2 O 18 vapour 899 conditions, Corrosion Science, vol.134, p.32, 2018.

A. Abdelouas, A Preliminary Investigation of the ISG Glass Vapor Hydration, 901 INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE, vol.4, issue.4, p.33, 2013.
URL : https://hal.archives-ouvertes.fr/in2p3-00919910

A. A. Chaou, The French SON68 glass vapor hydration under different atmospheres

, Procedia Materials Science, vol.904, p.34, 2014.

. Collectif, Référentiel du comportement des colis de déchets HA-MAVL -Tome 2 -Déchets vitrifiés, 905 ANDRA and CEA, vol.906, p.35, 2012.

W. L. Ebert and J. K. Bates, The reaction of synthetic nuclear waste glass in steam and 907 hydrothermal solution, vol.908, p.36, 1990.

W. L. Ebert, J. K. Bates, and W. L. Bourcier, The hydration of borosilicate waste glass in liquid 909 water and steam at 200° C. Waste Management, vol.11, p.37, 1991.

Y. Moriya and M. Nogami, Hydration of silicate glass in steam atmosphere, vol.38, p.38, 1980.

D. J. Wronkiewicz, J. E. Young, and J. K. Bates, Effects of alpha and gamma radiation on glass 913 reaction in an unsaturated environment, in Scientific Basis for Nuclear Waste Management, Mater. Res. Soc. p, vol.914, p.39, 1991.

F. Alloteau, New insight into atmospheric alteration of alkali-lime silicate glasses. 916 Corrosion Science, vol.122, p.40, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01663002

L. Sessegolo, Long-term weathering rate of stained-glass windows using H and O isotopes. 918 npj Materials Degradation, vol.2, p.41, 2018.

L. Gentaz, Role of secondary phases in the scaling of stained glass windows exposed to 920 rain, Corrosion Science, vol.109, p.42, 2016.

Y. Kudriavtsev, Water vapor interaction with borosilicate glass, Solid State Ionics, vol.922, p.43, 2018.

B. C. Bunker, Molecular mechanisms for corrosion of silica and silicate glasses, vol.179, p.44, 1994.

Y. Kudriavtsev, R. Asomoza-palacio, and L. Manzanilla-naim, Interaction of water vapor with 926 silicate glass surfaces: Mass-spectrometric investigations, Technical Physics Letters, vol.43, issue.5, p.45, 2017.

J. C. Cunnane, High-level nuclear-waste borosilicate glass : a compendium of 929 characteristics., in Scientific Basis for Nuclear Waste Management XVI

. Pabalan, Mater. Res. Soc, vol.931, p.46, 1993.

B. Thien, The dual effect of Mg on the long-term alteration rate of AVM nuclear waste 932 glasses, Journal of Nuclear Materials, vol.427, p.47, 2012.

B. Thien, Développement des bases théoriques nécessaires à la modélisation de la vitesse 934 résiduelle d'altération en milieu aqueux des verres nucléaires AVM. 2010, Université Montpellier 935 II, vol.936, p.48

H. Arena, Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects, Journal of Nuclear Materials, vol.937, pp.55-67, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01998377

H. Aréna, Impact of iron and magnesium on glass alteration: Characterization of the 939 secondary phases and determination of their solubility constants, Applied Geochemistry, vol.940, p.50, 2017.

H. Aréna, Impact of Fe, Mg and Ca elements on glass alteration: Interconnected processes. 942 Geochimica et Cosmochimica Acta, vol.239, p.51, 2018.

S. Mercado-depierre, Antagonist effects of calcium on borosilicate glass alteration, 944 Journal of Nuclear Materials, vol.441, issue.1-3, p.52, 2013.

P. Jollivet, Effect of clayey groundwater on the dissolution rate of the simulated nuclear 946 waste glass SON68, Journal of Nuclear Materials, vol.420, p.53, 2012.

C. Jegou, S. Gin, and F. Larche, Alteration kinetics of a simplified nuclear glass in an aqueous 948 medium: effects of solution chemistry and of protective gel properties on diminishing the 949 alteration rate, Journal of Nuclear Materials, vol.280, issue.2, p.54, 2000.

S. Gin, Effect of composition on the short-term and long-term dissolution rates of ten 951 glasses of increasing complexity from 3 to 30 oxides, Journal of Non-Crystalline Solids, vol.952, pp.2559-2570, 2012.

S. Gin, A. Abdelouas, L. J. Criscenti, W. L. Ebert, K. Ferrand et al., , p.954

Y. Mitsui, S. Mueller, K. T. Marra, J. C. Pantano, C. G. Pierce et al., , p.955

C. I. Steefel and J. D. Vienna, An international initiative on long-term behavior of high-level nuclear 956 waste glass. Materials Today, vol.16, p.56, 2013.

L. Trotignon, The compared aqueous corrosion of four simple borosilicate glasses: 958 Influence of Al, Ca, and Fe on the formation and nature of secondary phases, Journal of Nuclear 959 Materials, vol.190, p.57, 1992.

J. Neeway, Altération aqueuse et hydration en phase vapeur du verre SON68 à basse 963 température (35-90°C). 2014, L'Université Nantes Angers Le Mans, Bouakkaz, R, vol.962, issue.58, p.60, 2010.

M. Collin, Impact of alkali on the passivation of silicate glass. npj Materials Degradation, vol.2, p.61, 2018.
URL : https://hal.archives-ouvertes.fr/cea-01800770

F. Angeli, Structure and Chemical Durability of Lead Crystal Glass. Environmental Science 968 & Technology, vol.50, p.62, 2016.

O. Spalla, S. Lyonnard, and F. Testard, Analysis of the small-angle intensity scattered by a porous 970 and granular medium, Journal of Applied Crystallography, vol.36, p.63, 2003.

O. Spalla, Influence of insoluble elements on the nanostructure of water altered glasses, 972 Journal of Non-Crystalline Solids, vol.347, issue.1-3, p.64, 2004.

C. Cailleteau, Influence de la morphologie du gel sur la cinétique d'altération des verres 974 nucléaires: rôle du calcium et du zirconium, Thèse de l'école polytechnique de, vol.975, p.65, 2008.

B. M. Thien, A simple way to constrain the stoichiometry of secondary smectites upon aqueous 976 glass alteration, Applied Geochemistry, vol.42, p.66, 2014.

R. Jolyon and I. Chau, Mindat : base de données minéralogiques, vol.979, p.67

S. W. Bailey, Crystal Structures of Clay Minerals and Their X-ray Identification, vol.5, p.68, 1980.

G. W. Brindley and G. Brown, Crystal Structures of Clay Minerals and their X-ray identification

J. T. Kloprogge, S. Komarneni, and J. E. Amonette, Synthesis of smectite clay minerals a critical 984 review, Clays and Clay Minerals, vol.47, issue.5, pp.529-554, 1999.

H. Harder, The role of magnesium in the formation of smectite minerals, Chemical Geology, vol.10, issue.1, pp.31-39, 1972.

C. S. Pascua, H. Yamada, . Low-temperature, . Formation, and . Clay-minerals, 988 CORRELATING LABORATORY EXPERIMENTS WITH NATURAL FIELD-SCALE PROCESSES. Clay 989 Science, vol.16, p.72, 2012.

J. Joly, Phyllosilicates 2:1 trioctaédriques et leur procédé de préparation, E.P. Office, p.991

, IFP Energies Nouvelles France, vol.992, p.73, 1991.

M. Py, Study of interfaces and nanometric structures by ToF-SIMS : upon a spatially resolved 993 quantitative analysis, Micro and nanotechnologies/Microelectronics. 2011, Université de 994 Grenoble, vol.995, p.74

G. E. Romanos, Methods of evaluating pore morphology in hybrid organic-inorganic 996 porous materials, Microporous and Mesoporous Materials, vol.120, issue.1, p.75, 2009.

F. Alloteau, Contribution à la compréhension des mécanismes de l'altération atmosphérique des 998 verres et étude d'un traitement de protection à base de sels de zinc. Application à la conservation 999 des objets en verre du patrimoine culturel, vol.1001, p.76, 2017.

I. Biron, Émaux sur Métal -du IXe au XIXe Siècle, Technique et Matériaux. 2015: Faton 1002 edition, vol.1003, p.77

J. Sterpenich and G. Libourel, Using stained glass windows to understand the durability of toxic 1004 waste matrices, Chemical Geology, vol.174, p.78, 2001.

F. Commissariat-À-l'énergie, V. Centre-de, I. I. E.t.d.l.-université, and . Montpellier, Actes 1006 des journées sur le Verre: Université d'été CEA/VALRHÔ = CEA/VALRHÔ Summer Session 1007 proceedings Glass ; Recherche scientifique pour un confinement de haute performance = 1008 Scientific research for high performance containment, 31 août-7 septembre, J, vol.31, p.80, 1009.

M. S. Barger, D. K. Smith, and W. B. White, Characterization of corrosion products on old 1013 protective glass, especially daguerreotype cover glasses, Journal of Materials Science, vol.1015, issue.4, p.81, 1989.

D. Rebiscoul, Protective properties and dissolution ability of the gel formed during nuclear 1016 glass alteration, Journal of Nuclear Materials, vol.342, issue.1, p.82, 2005.

D. Rebiscoul, Morphological evolution of alteration layers formed during nuclear glass 1018 alteration: new evidence of a gel as a diffusive barrier, Journal of Nuclear Materials, vol.326, issue.1, p.83, 1019.

C. Cailleteau, Why Do Certain Glasses with a High Dissolution Rate Undergo a Low Degree 1021 of Corrosion?, The Journal of Physical Chemistry C, vol.115, issue.13, p.84, 2011.

L. Guillou and C. , New experimental approach to study aqueous alteration of amorphous 1023 silicates at low reaction rates, Chemical Geology, vol.412, p.85, 2015.

R. Balasubramanian, Investigation of the vaporization of boric acid by transpiration 1025 thermogravimetry and knudsen effusion mass spectrometry, J. Phys. Chem. B, vol.112, p.86, 2008.

J. Gaillardet, Evaporation and Sublimation of Boric Acid: Application for Boron Purification 1028 from Organic Rich Solutions, Geostandards Newsletter, vol.25, issue.1, p.87, 2001.

S. Siboni and C. D. Volpe, Some mathematical aspects of the Kelvin equation, Computers & 1030 Mathematics with Applications, vol.55, p.88, 2008.

L. Sicard, Study of the kinetics of glass alteration by small-angle X-ray scattering, Journal, vol.6