O. Dechy-cabaret, B. Martin-vaca, and D. Bourissou, Controlled Ring-Opening Polymerization of Lactide and Glycolide, Chemical Reviews, vol.104, issue.12, pp.6147-6176, 2004.

H. R. Kricheldorf and M. Sumbél, Polylactones?18. Polymerization of l,l-lactide with Sn(II) and Sn(IV) halogenides, European Polymer Journal, vol.25, issue.6, pp.585-591, 1989.

M. Wisniewski, A. L. Borgne, and N. Spassky, Synthesis and properties of (D)- and (L)-lactide stereocopolymers using the system achiral Schiff's base/aluminium methoxide as initiator, Macromolecular Chemistry and Physics, vol.198, issue.4, pp.1227-1238, 1997.

H. R. Kricheldorf, I. Kreiser-saunders, D. O. Damrau-;-c, P. G. Wheaton, B. J. Hayes et al., Complexes of Mg, Ca and Zn as homogeneous catalysts for lactide polymerization, Macromol. Symp, vol.159, pp.4832-4846, 2000.

A. Sauer, A. Kapelski, C. Fliedel, S. Dagorne, M. Kol et al., Structurally well-defined group 4 metal complexes as initiators for the ring-opening polymerization of lactide monomers, Dalton Transactions, vol.42, issue.25, p.9007, 2013.
URL : https://hal.archives-ouvertes.fr/hal-02120803

S. Jacobsen, H. G. Fritz, . Ph, P. Degée, R. Dubois et al., Single-step reactive extrusion of PLLA in a corotating twin-screw extruder promoted by 2-ethylhexanoic acid tin(II) salt and triphenylphosphine, Polymer, vol.41, pp.507-515, 2000.

O. Avinc, A. Khoddami-;-b, ). L. Shen, J. Haufe, and M. K. Patel, Product overview and market projection of emerging biobased plastics, pp.391-401, 2009.

H. Tsuji-;-a.-gallos, G. Fontaine, and S. Bourbigot, Reactive Extrusion of Stereocomplexed Poly-L, D-lactides: Processing, Characterization, and Properties, Poly(lactic acid) stereocomplexes: A decade of progress, vol.107, pp.1016-1023, 2013.

A. Hassan, H. Balakrishnan, and A. Akbari, Poly(lactic acid) Based Blends, Composites and Nanocomposites in Advances in Natural Polymers, pp.361-396, 2012.

M. L. De-castro, S. H. Wang, ;. E. Stirling, Y. Champouret, and M. Visseaux, Catalytic metal-based systems for controlled statistical copolymerisation of lactide with a lactone, Polymer Bulletin, vol.51, pp.2517-2531, 2003.

J. M. Vion, R. Jerome, P. Teyssie, M. Aubin, and R. E. Prudhomme, Synthesis, characterization, and miscibility of caprolactone random copolymers, Macromolecules, vol.19, issue.7, pp.1828-1838, 1986.

J. Mosnác?ek, A. Duda, J. Libiszowski, and S. Penczek, Copolymerization ofll-Lactide at Its Living Polymer?Monomer Equilibrium with ?-Caprolactone as Comonomer, Macromolecules, vol.38, issue.6, pp.2027-2029, 2005.

J. P. Brutman, P. A. Delgado, and M. A. Hillmyer, Polylactide Vitrimers, ACS Macro Letters, vol.3, issue.7, pp.607-610, 2014.

G. Fornasieri, L. Rozes, S. Le-calvé, B. Alonso, D. Massiot et al., Reactivity of Titanium Oxo Ethoxo Cluster [Ti16O16(OEt)32]. Versatile Precursor of Nanobuilding Block-Based Hybrid Materials, Journal of the American Chemical Society, vol.127, issue.13, pp.4869-4878, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00016853

G. Fornasieri, L. Rozes, S. Le-calvé, B. Alonso, D. Massiot et al., Reactivity of Titanium Oxo Ethoxo Cluster [Ti16O16(OEt)32]. Versatile Precursor of Nanobuilding Block-Based Hybrid Materials, Journal of the American Chemical Society, vol.127, issue.13, pp.4869-4878, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00016853

S. Bocchini, G. Fornasieri, L. Rozes, S. Trabelsi, J. Galy et al., New hybrid organic?inorganic nanocomposites based on functional [Ti16O16(OEt)24(OEMA)8] nano-fillers, Chemical Communications, vol.20, issue.20, p.2600, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00022616

G. Soler-illia, L. Rozes, M. K. Boggiano, C. Sanchez, C. Turrin et al., New mesotextured hybrid materials made from assemblies of dendrimers and titanium(IV)-oxo-organo clusters, Angew. Chem. Int. Ed, vol.39, pp.4250-4254, 2000.

F. Périneau, S. Pensec, C. Sassoye, F. Ribot, L. Van-lokeren et al., New hybrid core?shell star-like architectures made of poly(n-butyl acrylate) grown from well-defined titanium oxo-clusters, Journal of Materials Chemistry, vol.21, issue.12, p.4470, 2011.

F. Périneau, S. Pensec, C. Sanchez, C. Creton, L. Rozes et al., Supramolecular design for polymer/titanium oxo-cluster hybrids: an open door to new organic?inorganic dynamers, Polymer Chemistry, vol.2, issue.12, p.2785, 2011.

E. W. Fischer, H. J. Sterzel, and G. Wegner, Investigation of the structure of solution grown crystals of lactide copolymers by means of chemical reactions, Kolloid-Zeitschrift und Zeitschrift für Polymere, vol.251, issue.11, pp.980-990, 1973.