, Les retardateurs de flamme-Questions les plus courantes, 2010.

S. Bourbigot and X. Flambard, Heat resistance and flammability of high performance fibres: A review, Fire Mater, vol.26, pp.155-168, 2002.

D. Q. Chen, Y. Z. Wang, X. P. Hu, D. Y. Wang, M. H. Qu et al., Flame-retardant and anti-dripping effects of a novel char-forming flame retardant for the treatment of poly(ethylene terephthalate) fabrics, Polym. Degrad. Stab, vol.88, pp.349-356, 2005.

J. Choi, A. F. Yee, and R. M. Laine, Organic/inorganic hybrid composites from cubic silsesquioxanes. epoxy resins of octa(dimethylsiloxyethylcyclohexylepoxide) silsesquioxane, Macromolecules, vol.36, pp.5666-5682, 2003.

S. Y. Lu, Hamerton, I. Recent developments in the chemistry of halogen-free flame retardant polymers, Prog. Polym. Sci, vol.27, pp.1661-1712, 2002.

S. Bourbigot, M. Le-bras, S. Duquesne, and M. Rochery, Recent advances for intumescent polymers, Macromol. Mater. Eng, vol.289, pp.499-511, 2004.

S. Bourbigot, M. Le-bras, R. Leeuwendal, K. K. Shen, and D. Schubert, Recent advances in the use of zinc borates in flame retardancy of EVA, Polym. Degrad. Stab, vol.64, pp.419-425, 1999.

S. V. Levchik and E. D. Weil, Thermal decomposition, combustion and flame-retardancy of epoxy resins-A review of the recent literature, Polym. Int, vol.53, pp.1901-1929, 2004.

E. Health, , 2010.

E. Manias, G. Polizos, H. Nakajima, and M. J. Heidecker, Fundamentals of Polymer Nanocomposite Technology, Flame Retardant Polymer Nanocomposites

A. B. Morgan and C. A. Wilkie, , 2007.

F. Samyn, S. Bourbigot, C. Jama, and S. Bellayer, Fire retardancy of polymer clay nanocomposites: Is there an influence of the nanomorphology?, Polym. Degrad. Stab, vol.93, pp.2019-2024, 2008.

A. Hartwig, D. Pütz, B. Schartel, M. Bartholmai, and M. Wendschuh-josties, Combustion Behaviour of Epoxide Based Nanocomposites with Ammonium and Phosphonium Bentonites, Macromol. Chem. Phys, vol.204, pp.2247-2257, 2003.

B. Schartel, U. Knoll, A. Hartwig, and D. Pütz, Phosphonium-modified layered silicate epoxy resins nanocomposites and their combinations with ATH and organo-phosphorus fire retardants, Polym. Adv. Technol, vol.17, pp.281-293, 2006.

B. W. Schartel, H. Sturm, M. Kleemeier, A. Hartwig, C. Vogt et al., Layered silicate epoxy nanocomposites: formation of the inorganic-carbonaceous fire protection layer, Polym. Adv. Technol, 2010.

G. Camino, G. Tartaglione, A. Frache, C. Manferti, and G. Costa, Thermal and combustion behaviour of layered silicate-epoxy nanocomposites, Polym. Degrad. Stab, vol.90, pp.354-362, 2005.

M. Zammarano, Thermoset Fire Retardant Nanocomposites, Flame Retardant Polymer Nanocomposites

A. B. Morgan and C. A. Wilkie, , pp.235-284, 2007.

L. Torre, E. Frulloni, J. M. Kenny, C. Manferti, and G. Camino, Processing and characterization of epoxy-anhydride-based intercalated nanocomposites, J. Appl. Polym. Sci, vol.90, pp.2532-2539, 2003.

M. Zammarano, M. Franceschi, S. Bellayer, J. W. Gilman, and S. Meriani, Preparation and flame resistance properties of revolutionary self-extinguishing epoxy nanocomposites based on layered double hydroxides, Polymer, vol.46, pp.9314-9328, 2005.

J. Brus, M. Urbanova, and A. Strachota, Epoxy networks reinforced with polyhedral oligomeric silsesquioxanes: Structure and segmental dynamics as studied by solid-state NMR, Macromolecules, vol.41, pp.372-386, 2008.

J. Fu, L. Shi, Y. Chen, S. Yuan, J. Wu et al., Epoxy nanocomposites containing mercaptopropyl polyhedral oligomeric silsesquioxane: Morphology, thermal properties, and toughening mechanism, J. Appl. Polym. Sci, vol.109, pp.340-349, 2008.

Z. Zhang, G. Liang, J. Wang, and P. Ren, Epoxy/POSS organic-inorganic hybrids: Viscoelastic, mechanical properties and micromorphologies, Polym. Compos, vol.28, pp.175-179, 2007.

A. Vannier, S. Duquesne, S. Bourbigot, J. Alongi, G. Camino et al., Investigation of the thermal degradation of PET, zinc phosphinate, OMPOSS and their blends-Identification of the formed species, Thermochim. Acta, vol.495, pp.155-166, 2009.

A. Vannier, S. Duquesne, S. Bourbigot, A. Castrovinci, G. Camino et al., The use of POSS as synergist in intumescent recycled poly(ethylene terephthalate), Polym. Degrad. Stab, vol.93, pp.818-826, 2008.

S. Bourbigot, S. Duquesne, G. Fontaine, S. Bellayer, T. Turf et al., Characterization and Reaction to Fire of Polymer Nanocomposites with and without Conventional Flame Retardants, Mol. Cryst. Liq. Cryst, vol.486, pp.325-339, 2008.

T. Lu, G. Liang, Y. Peng, and T. Chen, Blended hybrids based on silsesquioxane-OH and epoxy resins, J. Appl. Polym. Sci, vol.106, pp.4117-4123, 2007.

T. Lu, T. Chen, and G. Liang, Synthesis, thermal properties, and flame retardance of the epoxysilsesquioxane hybrid resins, Polym. Eng. Sci, vol.47, pp.225-234, 2007.

K. Wu, L. Song, Y. Hu, H. Lu, B. K. Kandola et al., Synthesis and characterization of a functional polyhedral oligomeric silsesquioxane and its flame retardancy in epoxy resin, Prog. Org. Coat, vol.65, pp.490-497, 2009.

Q. Wu, C. Zhang, R. Liang, and B. Wang, Combustion and thermal properties of epoxy/phenyltrisilanol polyhedral oligomeric silsesquioxane nanocomposites, J. Therm. Anal. Calorim, pp.1-7, 2009.

X. Wang, Y. Hu, L. Song, W. Xing, and H. Lu, Thermal degradation behaviors of epoxy resin/poss hybrids and phosphorus-silicon synergism of flame retardancy, J. Polym. Sci.B, vol.48, pp.693-705, 2010.

E. Franchini, J. Galy, J. F. Gérard, D. Tabuani, and A. Medici, Influence of POSS structure on the fire retardant properties of epoxy hybrid networks, Polym. Degrad. Stab, vol.94, pp.1728-1736, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00987379

T. Kashiwagi, F. Du, K. I. Winey, K. M. Groth, J. R. Shields et al., Flammability properties of polymer nanocomposites with single-walled carbon nanotubes: Effects of nanotube dispersion and concentration, Polymer, vol.46, pp.471-481, 2005.

T. Kashiwagi, E. Grulke, J. Hilding, K. Groth, R. Harris et al., Thermal and flammability properties of polypropylene/carbon nanotube nanocomposites, Polymer, vol.45, pp.4227-4239, 2004.

C. F. Kuan, W. J. Chen, Y. L. Li, C. H. Chen, H. C. Kuan et al., Flame retardance and thermal stability of carbon nanotube epoxy composite prepared from sol-gel method, J. Phys. Chem. Solids, vol.71, pp.539-543, 2010.

S. S. Rahatekar, M. Zammarano, S. Matko, K. K. Koziol, A. H. Windle et al., Effect of carbon nanotubes and montmorillonite on the flammability of epoxy nanocomposites, Polym. Degrad. Stab, vol.95, pp.870-879, 2010.

M. Jimenez, S. Duquesne, and S. Bourbigot, Characterization of the performance of an intumescent fire protective coating, Surf. Coat. Technol, vol.201, pp.979-987, 2006.

L. S. Wang, X. L. Wang, and G. L. Yan, Synthesis, characterization and flame retardance behaviour of poly(ethylene terephthalate) copolymer containing triaryl phosphine oxide, Polym. Degrad. Stab, vol.69, pp.127-130, 2000.

G. Fontaine, S. Bourbigot, and S. Duquesne, Neutralized flame retardant phosphorus agent: Facile synthesis, reaction to fire in PP and synergy with zinc borate, Polym. Degrad. Stab, vol.93, pp.68-76, 2008.

F. Samyn, S. Bourbigot, C. Jama, S. Bellayer, S. Nazare et al., Characterisation of the dispersion in polymer flame retarded nanocomposites, Eur. Polym. J, vol.44, pp.1631-1641, 2008.

S. Levchik, A. Piotrowski, E. Weil, and Q. Yao, New developments in flame retardancy of epoxy resins, Polym. Degrad. Stab, vol.88, pp.57-62, 2005.

S. V. Levchik and E. D. Weil, A review of recent progress in phosphorus-based flame retardants, J. Fire Sci, vol.24, pp.345-364, 2006.

P. Jain, V. Choudhary, and I. K. Varma, Flame retarding epoxies with phosphorus, J. Macromol. Sci, vol.42, pp.139-183, 2002.

M. Hussain, R. J. Varley, Z. Mathys, Y. B. Cheng, and G. P. Simon, Effect of Organo-Phosphorus and Nano-Clay Materials on the Thermal and Fire Performance of Epoxy Resins, J. Appl. Polym. Sci, vol.91, pp.1233-1253, 2004.

C. S. Wang and C. Lin-hsuan, Synthesis and properties of phosphorus-containing epoxy resins by novel method, J. Polym. Sci., Part A: Polym. Chem, vol.37, pp.3903-3909, 1999.

C. H. Lin and C. S. Wang, Novel phosphorus-containing epoxy resins Part I. Synthesis and properties, Polymer, vol.42, pp.1869-1878, 2001.

M. Ciesielski, A. Schäfer, and M. Döring, Novel efficient DOPO-based flame-retardants for PWB relevant epoxy resins with high glass transition temperatures, Polym. Adv. Technol, vol.19, pp.507-515, 2008.

A. Schäfer, S. Seibold, W. Lohstroh, O. Walter, and M. Döring, Synthesis and properties of flame-retardant epoxy resins based on DOPO and one of its analog DPPO, J. Appl. Polym. Sci, vol.105, pp.685-696, 2007.

P. M. Hergenrother, C. M. Thompson, J. G. Smith, J. W. Connell, J. A. Hinkley et al., Flame retardant aircraft epoxy resins containing phosphorus, Polymer, vol.46, pp.5012-5024, 2005.

U. Braun, A. I. Balabanovich, B. Schartel, U. Knoll, J. Artner et al., Influence of the oxidation state of phosphorus on the decomposition and fire behaviour of flame-retarded epoxy resin composites, Polymer, vol.47, pp.8495-8508, 2006.

P. Kiliaris and C. D. Papaspyrides, Polymer/layered silicate (clay) nanocomposites: An overview of flame retardancy, Prog. Polym. Sci, 2010.

W. Liu, R. J. Varley, and G. P. Simon, Understanding the decomposition and fire performance processes in phosphorus and nanomodified high performance epoxy resins and composites, Polymer, vol.48, pp.2345-2354, 2007.

A. Toldy, N. Toth, P. Anna, and G. Marosi, Synthesis of phosphorus-based flame retardant systems and their use in an epoxy resin, Polym. Degrad. Stab, vol.91, pp.585-592, 2006.

A. Toldy, N. Toth, P. Anna, G. Keglevich, K. Kiss et al., Flame retardancy of epoxy resin with phosphorus-containing reactive amine and clay minerals, Polym. Adv. Technol, vol.17, pp.778-781, 2006.

L. A. Mercado, J. A. Reina, and M. Galià, Flame Retardant Epoxy Resins Based on Diglycidyloxymethylphenylsilane, J. Polym. Sci., Part A: Polym. Chem, vol.44, pp.5580-5587, 2006.

J. Canadell, A. Mantecon, and V. Càdiz, Novel silicon-containing spiroorthoester to confer combined flame retardancy and low shrinkage properties to epoxy resins, J. Polym. Sci., Part A: Polym. Chem, vol.45, pp.4211-4224, 2007.

J. Canadell, A. Mantecon, and V. Cadiz, Copolymerization of a silicon-containing spiroorthoester with a phosphorus-containing diglycidyl compound: Influence on flame retardancy and shrinkage, Polym. Degrad. Stab, vol.92, pp.1934-1941, 2007.

M. Harada, S. Minamigawa, and M. Ochi, Thermal properties and flame retardancy of polyglycidyloxypropyl silsesquioxane/layered titanate nanocomposites, J. Appl. Polym. Sci, vol.110, pp.2649-2655, 2008.

M. Harada, S. Minamigawa, K. Tachibana, and M. Ochi, Flame retardancy and thermomechanical properties of the poly-(glycidyloxypropyl) phenyl silsesquioxane/ layered titanate nanocomposites, J. Appl. Polym. Sci, vol.106, pp.338-344, 2007.

G. H. Hsiue, W. J. Wang, and F. C. Chang, Synthesis, characterization, thermal and flame-retardant properties of silicon-based epoxy resins, J. Appl. Polym. Sci, vol.73, pp.1231-1238, 1999.

M. Jimenez, S. Duquesne, and S. Bourbigot, Intumescent fire protective coating: Toward a better understanding of their mechanism of action, Thermochim. Acta, vol.449, pp.16-26, 2006.

M. Jimenez, S. Duquesne, and S. Bourbigot, Kinetic analysis of the thermal degradation of an epoxybased intumescent coating, Polym. Degrad. Stab, vol.94, pp.404-409, 2009.

H. Wang, J. Liu, S. Xu, and W. Shi, Preparation and film properties of tri(3,4-epoxycyclohexylmethyl) phosphate based cationically UV curing coatings, Prog. Org. Coat, vol.65, pp.263-268, 2009.

G. Wang and J. Yang, Influences of binder on fire protection and anticorrosion properties of intumescent fire resistive coating for steel structure, Surf. Coat. Technol, vol.204, pp.1186-1192, 2010.

Z. Wang, E. Han, and W. Ke, Influence of nano-LDHs on char formation and fire-resistant properties of flame-retardant coating, Prog. Org. Coat, vol.53, pp.29-37, 2005.

Z. Wang, E. Han, and W. Ke, Effect of nanoparticles on the improvement in fire-resistant and antiageing properties of flame-retardant coating, Surf. Coat. Technol, pp.5706-5716, 0200.

Z. Wang, E. Han, F. Liu, and W. Ke, Thermal behavior of nano-TiO 2 in fire-resistant coating, J. Mater. Sci. Technol, vol.23, pp.547-550, 2007.

A. Castrovinci, G. Camino, C. Drevelle, S. Duquesne, C. Magniez et al., Ammonium polyphosphate-aluminum trihydroxide antagonism in fire retarded butadiene-styrene block copolymer, Eur. Polym. J, vol.41, pp.2023-2033, 2005.