2-Amino-1-(4-aminophenyl)-1H-pyrrolo(2,3-b)quinoxaline-3- carbonitrile as an efficient inhibitor for the corrosion of C38 steel in hydrochloric acid solution
Abstract : The inhibiting properties of 2-Amino-1-(4-aminophenyl)-1H-pyrrolo(2,3-b)quinoxaline-3-carbonitrile (AHPQC) were examined of C38 steel corrosion in molar hydrochloric acid using electrochemical techniques. Impedance data displayed the AHPQC inhibits C38 steel corrosion becoming the adsorbate at metal/electrolyte interfaces. Polarization study indicated that AHPQC is an anodic-cathodic inhibitor. The inhibition efficiencies of AHPQC calculated by both methods reaches 91%. The Langmuir adsorption isotherm was observed for the AHPQC adsorption and its adsorption is realized by physical adsorption; due to the protonated forms of the AHPQC molecule in acid medium. XPS technique was used to discuss the mechanism for the adsorption process of the AHPQC molecule.
https://hal.univ-lille.fr/hal-02927036
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Soumis le : mardi 1 septembre 2020 - 12:15:08 Dernière modification le : mardi 13 octobre 2020 - 14:57:54 Archivage à long terme le : : mercredi 2 décembre 2020 - 13:38:39
Mounim Lebrini, W. Benkayba, Charafeddine Jama, Fouad Bentiss, Christophe Roos. 2-Amino-1-(4-aminophenyl)-1H-pyrrolo(2,3-b)quinoxaline-3- carbonitrile as an efficient inhibitor for the corrosion of C38 steel in hydrochloric acid solution. International Journal of Electrochemical Science, ESG 2020, 15, pp.2326-2334. ⟨10.20964/2020.03.46⟩. ⟨hal-02927036⟩