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Support-Induced Effects of LaFeO3Perovskite on the Catalytic Performances of Supported Pt Catalysts in DeNOxApplications

Abstract : A comparative investigation of the catalytic performance in the simultaneous conversion of NOx and N2O has been achieved on supported nanosized Pt particles interacting with conventional alumina and perovskite based materials. Particular attention has been paid to successive thermal treatments under reductive and oxidative atmospheres which induce bulk and surface reconstructions. Those modifications considerably alter the catalytic behavior of Pt in interaction with LaFeO3 or γ-Al2O3 in terms of activity and selectivity toward the selective transformation of NOx to nitrogen at low temperature. Changes in physicochemical properties have been examined using appropriate techniques, such as H2-temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), and Fourier transform infrared (FTIR) of CO adsorption. It has been found that oxidic Pt4+ species initially stabilized on LaFeO3 lead after subsequent H2 reduction to the formation of metallic nano-Pt particles in stronger interaction than on γ-Al2O3 support and then become more resistant to sintering during thermal aging in 1000 ppm NO, 1000 ppm N2O, 3 vol % O2, 0.5 vol % H2O, and 0.5 vol % H2 at 500 °C. Correlatively, significant improvements have been observed in the selective reduction of NOx to nitrogen. This study opens new prospects in the development of supported catalysts containing low Pt loadings because of the existence of stronger interactions with perovskite supports.
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Soumis le : vendredi 11 décembre 2020 - 15:38:11
Dernière modification le : mercredi 23 mars 2022 - 15:51:10




Jean-Philippe Dacquin, Christine Lancelot, Christophe Dujardin, Catherine Cordier, Pascal Granger. Support-Induced Effects of LaFeO3Perovskite on the Catalytic Performances of Supported Pt Catalysts in DeNOxApplications. Journal of Physical Chemistry C, American Chemical Society, 2011, The Journal of Physical Chemistry C, 115 (5), pp.1911-1921. ⟨10.1021/jp1069779⟩. ⟨hal-03056222⟩



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