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Article dans une revue

Organocatalytic sequential ring-opening polymerization of a cyclic ester and anionic polymerization of a vinyl monomer

Abstract : Organocatalysis has provided new tools for making block copolymers, in particular active species able to polymerize monomers of different chemical nature such as cyclic esters, cyclic carbonates and epoxides. We report herein the first example of an organocatalytic active species able to polymerize sequentially a cyclic ester, ε-decalactone, and a vinyl monomer, methyl methacrylate. The resulting block copolymer shows the properties of thermoplastic elastomers.
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https://hal.univ-lille.fr/hal-03230829
Contributeur : Lilloa Université de Lille <>
Soumis le : jeudi 20 mai 2021 - 12:39:38
Dernière modification le : vendredi 21 mai 2021 - 03:28:46

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Distributed under a Creative Commons Paternité - Pas de modifications 4.0 International License

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Robert Mundil, Franck Kayser, Audrey Favrelle-Huret, Grégory Stoclet, Philippe Zinck. Organocatalytic sequential ring-opening polymerization of a cyclic ester and anionic polymerization of a vinyl monomer. Chemical Communications, Royal Society of Chemistry, 2020, 56 (58), pp.8067-8070. ⟨10.1039/D0CC02906H⟩. ⟨hal-03230829⟩

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