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Selective aqueous phase hydrogenation of xylose to xylitol over SiO2-supported Ni and Ni-Fe catalysts: Benefits of promotion by Fe

Abstract : A monometallic Ni and a bimetallic Ni-Fe catalyst were used in the aqueous phase hydrogenation of xylose in batch conditions (T = 50–150 °C, PH2 = 10–30 bar, xylose mass fraction in water = 3.7–11.0 wt.%) to evidence the benefits of promoting Ni by Fe. The activity of the catalysts increased with temperature, but a temperature of 80 °C allowed minimizing nickel leaching at full conversion. The presence of reduced Fe at the surface of the bimetallic nanoparticles increased both the first-order apparent rate constant and the adsorption constant of xylose. The catalytic activity of Ni/SiO2 strongly declined and no deactivation was found for the Ni-Fe catalyst. A restructuring of the bimetallic nanoparticles took place, as the size of the metal particles and the Fe proportion in the surface layers increased, suggesting a flattening and coalescing of the particles over the silica surface.
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https://hal.univ-lille.fr/hal-03319802
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Soumis le : mercredi 6 octobre 2021 - 08:58:39
Dernière modification le : vendredi 1 avril 2022 - 03:52:33
Archivage à long terme le : : vendredi 7 janvier 2022 - 18:13:29

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Achraf Sadier, Dichao Shi, Anne-Sophie Mamede, Sébastien Paul, Eric Marceau, et al.. Selective aqueous phase hydrogenation of xylose to xylitol over SiO2-supported Ni and Ni-Fe catalysts: Benefits of promotion by Fe. Applied Catalysis B: Environmental, Elsevier, 2021, 298, pp.120564. ⟨10.1016/j.apcatb.2021.120564⟩. ⟨hal-03319802⟩

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