1:1 Ca2+:Cu2+ A-site order in a ferrimagnetic double double perovskite - Université de Lille Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2022

1:1 Ca2+:Cu2+ A-site order in a ferrimagnetic double double perovskite

Résumé

Cation ordering in ABX3 perovskites is important to structural, physical and chemical properties. Here we report discovery of CaCuFeReO6 with the tetragonal AA′BB′O6 double double perovskite structure that was previously only reported for A′=Mn compositions. CaCuFeReO6 occurs in the same phase field as CaCu3Fe2Re2O12 demonstrating that different A-cation ordered peroskites may be obtained in the same chemical system. CaCuFeReO6 has ferrimagnetic order of Fe, Re and Cu spins below TC=567 K, in contrast to Mn analogues where the Mn spins order separately at much lower temperatures. The magnetoresistance of CaCuFeReO6 displays low-field “butterfly” hysteresis with an unusual change from negative to positive values as field increases. Many more AA′BB′O6 double double perovskites may be accessible for A′=Cu and other divalent transition metals at high pressure, so the presently known phases likely represent only the “tip of the iceberg” for this family.
Fichier principal
Vignette du fichier
A-site Order in a Ferrimagnetic Double Double Perovskite.pdf (1.69 Mo) Télécharger le fichier
Origine Fichiers éditeurs autorisés sur une archive ouverte

Dates et versions

hal-04142726 , version 1 (27-06-2023)

Licence

Identifiants

Citer

Elena Solana Madruga, Padraig S. Kearins, Clemens Ritter, Angel Arevalo Lopez, J. Paul Attfield. 1:1 Ca2+:Cu2+ A-site order in a ferrimagnetic double double perovskite. Angewandte Chemie International Edition, 2022, 61 (40), pp.e202209497. ⟨10.1002/anie.202209497⟩. ⟨hal-04142726⟩
3 Consultations
10 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More