TiO2 nanoparticle dispersions in water and nonaqueous solvents studied by gravitational sedimentation analysis: Complementarity of Hansen Parameters and DLVO interpretations - Université de Lille Accéder directement au contenu
Article Dans Une Revue Colloids and Surfaces A: Physicochemical and Engineering Aspects Année : 2021

TiO2 nanoparticle dispersions in water and nonaqueous solvents studied by gravitational sedimentation analysis: Complementarity of Hansen Parameters and DLVO interpretations

Résumé

Hansen Solubility Parameters (HSP) have been shown to be an effective approach for rationalizing and predicting the stability of titanium dioxide nanoparticles (TiO2 NPs) dispersions. However, interparticle electrostatic interactions, not considered in Hansen’s approach but taken into account in the DLVO theory, are expected to play a significant role in organic solvents having a notable dielectric constant. Zeta potential ζ of TiO2 P25 NPs was measured in both aqueous and organic media to identify DLVO-stabilized dispersions from those stabilized by more specific NP-solvent interaction. Stability was quantified using a Turbiscan optical device which provides Stokes diameters and Relative Turbiscan Stability Index (RTSI). When the zeta potential of NPs and the dielectric constant of the solvent are both high, the dispersion benefits from additional stabilization while when the electrostatic repulsion is negligible, only the solvents within a Hansen dispersion sphere give stable dispersions. The two interpretations are therefore complementary to describe the behavior of TiO2 dispersions in organic solvents.

Domaines

Chimie organique

Dates et versions

hal-04309454 , version 1 (27-11-2023)

Identifiants

Citer

Lucie Delforce, Véronique Rataj, Véronique Rataj, Jean-Marie Aubry. TiO2 nanoparticle dispersions in water and nonaqueous solvents studied by gravitational sedimentation analysis: Complementarity of Hansen Parameters and DLVO interpretations. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, Colloids and Surfaces A. Physicochemical and Engineering Aspects, 628, pp.127333. ⟨10.1016/j.colsurfa.2021.127333⟩. ⟨hal-04309454⟩
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