Article Dans Une Revue Applied Catalysis A : General Année : 2021

From useless humins by-product to Nb@graphite-like carbon catalysts highly efficient in HMF synthesis

Résumé

Highly dispersed supported NbOx species were prepared via a deposition precipitation-carbonization (DPC)-like method. As precursors for niobium species and carrier ammonium niobate(V) oxalate hydrate and humins were used. Characterization of the resulted catalysts indicated bi-functional acid-base niobium species anchored onto a highly hydrophobic graphite-like carbon structure. These catalysts were investigated in the one-pot conversion of glucose to 5-hydroxymethylfurfural (HMF) in a biphasic system consisting of a mixture of a 20 wt% NaCl aqueous solution phase and an organic extracting phase (methyl-isobutyl-ketone (MIBK), 2-tert-butylphenol (TBP) or 2-sec-butylphenol (SBP)). The optimization conditions afforded the highest yield to HMF (96 %) for the GHNb1.2 catalyst (with 2.5 wt%Nb), the base/acid sites ratio of 1.76, in biphasic TBP/water system, at 180 °C after 8 h.

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Catalyse
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hal-04442462 , version 1 (22-07-2024)

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Magdi El Fergani, Natalia Candu, Madalina Tudorache, Cristina Bucur, Nora Djelal, et al.. From useless humins by-product to Nb@graphite-like carbon catalysts highly efficient in HMF synthesis. Applied Catalysis A : General, 2021, Applied Catalysis A : General, 618, pp.118130. ⟨10.1016/j.apcata.2021.118130⟩. ⟨hal-04442462⟩
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