Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa - Université de Lille Accéder directement au contenu
Article Dans Une Revue Journal of Chemical and Engineering Data Année : 2021

Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa

Résumé

In this work, isobaric vapor–liquid equilibrium (VLE) measurements were conducted for the binary systems of prop-2-en-1-ol (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–hexan-2-one (2), hexan-2-one (1)–hexan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-ol (2), prop-2-en-1-ol (1)–4-methyl-pentan-2-one (2), and 4-methyl-pentan-2-one (1)–4-methyl-pentan-2-ol (2) to assist with the design of the separation process by distillation. Measurements were determined using Fischer VLE 602 equipment at 101.32 kPa. The thermodynamic consistency of the measured VLE data was validated by modified Herington, Van Ness, pure component consistency, and Redlich–Kister total area tests. Moreover, data sets were correlated using the nonrandom two-liquid (NRTL), universal quasichemical (UNIQUAC), and Wilson thermodynamic models to obtain the binary interaction parameters using the Aspen Plus V11 commercial software. The root-mean-square deviations (RMSDs) of the equilibrium temperature (T) and the vapor mole fraction (yi) were less than 0.24 and 0.0089, respectively, which indicate that these three thermodynamic models can be used to correlate the six binary systems and therefore they can be employed for the development and optimization of the separation process.

Domaines

Catalyse
Fichier principal
Vignette du fichier
Article-2- EVL-Final version.pdf (771.22 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-04467854 , version 1 (20-02-2024)

Identifiants

Citer

Karen Silva, Benjamin Katryniok, Marcia Carolina Araque Marin. Isobaric Vapor–Liquid Equilibrium Data for Six Binary Systems: Prop-2-en-1-ol (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–Hexan-2-one (2), Hexan-2-one (1)–Hexan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-ol (2), Prop-2-en-1-ol (1)–4-Methyl-pentan-2-one (2), and 4-Methyl-pentan-2-one (1)–4-Methyl-pentan-2-ol (2) at 101.32 kPa. Journal of Chemical and Engineering Data, 2021, Journal of Chemical and Engineering Data, 66 (2), pp.1055-1067. ⟨10.1021/acs.jced.0c00861⟩. ⟨hal-04467854⟩
1 Consultations
1 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More