Pentamethylcyclopentadienyl Ir(III) metallacycles: recent developments in catalysis
Résumé
Iridium (III) metallacycles have been applied successfully in organic transformations and in processes relevant to energy and environmental sciences. The ongoing interest for these complexes and their corresponding catalysts has led to new developments taking a strong advantage of the properties imparted by the chelate carboligand. Recent publications in this field are highlighted in order to underline the usefulness of such catalysts in oxygen and hydrogen production as well as for hydrodefluorination and hydrosilylation reactions for the synthesis of bulk and fine chemicals.
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