Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction - Université de Lille Accéder directement au contenu
Article Dans Une Revue Molecular Catalysis Année : 2017

Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction

Résumé

The catalytic hydroalkoxylation of butadiene with glycerol has been performed for the first time thanks to the use of nickel catalysts and an appropriate solvent. Optimization of the reaction conditions allowed obtaining 100% glycerol conversion into a mixture of glyceryl mono- and dibutenyl ethers. The experimental protocols used involved batch experiments or continuous feeding of butadiene at atmospheric pressure. The reaction has then been scaled up to produce multigrams of each pure monoethers and diethers according to simple decantation/distillation procedures. The ethers were further hydrogenated to their corresponding alkyl glyceryl ethers.
Fichier non déposé

Dates et versions

hal-03184714 , version 1 (29-03-2021)

Identifiants

Citer

Alexis Mifleur, Andre Mortreux, Isabelle Suisse, Mathieu Sauthier. Synthesis of C4 chain glyceryl ethers via nickel-catalyzed butadiene hydroalkoxylation reaction. Molecular Catalysis, 2017, Molecular Catalysis, 427, pp.25-30. ⟨10.1016/j.molcata.2016.11.022⟩. ⟨hal-03184714⟩
97 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More