Acyl Poly(Glycerol-Succinic Acid) Oligoesters: Synthesis, Physicochemical and Functional Properties, and Biodegradability - Université de Lille Accéder directement au contenu
Article Dans Une Revue Journal of Surfactants and Detergents Année : 2016

Acyl Poly(Glycerol-Succinic Acid) Oligoesters: Synthesis, Physicochemical and Functional Properties, and Biodegradability

Sinisa Marinkovic
  • Fonction : Auteur
Boris Estrine
  • Fonction : Auteur

Résumé

Biobased surfactants were synthesized using poly(glycerol-succinate) as the polar head group and variable acyl groups as hydrophobic tails. Acyl chain lengths ranged from 8 to 14 carbon atoms. The resulting oligomeric surfactants were characterized by quantitative 13C nuclear magnetic resonance (NMR), acid values and size exclusion chromatography. Investigation of the physicochemical properties of the acyl poly(glycerol-succinate) surfactants revealed their potential for use in a wide array of applications. The acyl poly(glycerol-succinate) functional properties appeared to be particularly concentration-dependent. This study highlights the relative impact of acyl chain length on the polymeric structure, physicochemical and functional behaviors, and biodegradability of the acyl poly(glycerol-succinate) surfactants.

Domaines

Chimie organique
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Dates et versions

hal-04556487 , version 1 (23-04-2024)

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Citer

Mickaël Agach, Sinisa Marinkovic, Boris Estrine, Véronique Nardello-Rataj. Acyl Poly(Glycerol-Succinic Acid) Oligoesters: Synthesis, Physicochemical and Functional Properties, and Biodegradability. Journal of Surfactants and Detergents, 2016, Journal of Surfactants and Detergents, 19, pp.933-941. ⟨10.1007/s11743-016-1853-4⟩. ⟨hal-04556487⟩
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