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Article Dans Une Revue Organic Letters Année : 2009

Selective Discrimination of Cyclodextrin Diols Using Cyclic Sulfates

Résumé

A method for selective monofunctionalition of readily available cyclodextrin diols (2A−F,3A−F,6B,C,E,F-hexadeca-O-benzyl-α-cyclodextrin and 2A−G,3A−G,6B,C,E−G-nonadeca-O-benzyl-β-cyclodextrin) by regioselective nucleophilic opening of their cyclic sulfates is presented. Although the A and D products are nonequivalent in β-cyclodextrin, only the A product is formed.

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Chimie
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Dates et versions

hal-04558901 , version 1 (25-04-2024)

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Marta Petrillo, Lavinia Marinescu, Cyril Rousseau, Mikael Bols. Selective Discrimination of Cyclodextrin Diols Using Cyclic Sulfates. Organic Letters, 2009, Organic Letters, 11, pp.1983-1985. ⟨10.1021/ol900413s⟩. ⟨hal-04558901⟩
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