Al-4(OH)(2)(OCH3)(4)(H2N-bdc)(3)]center dot xH(2)O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick - Université de Lille Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2009

Al-4(OH)(2)(OCH3)(4)(H2N-bdc)(3)]center dot xH(2)O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick

Résumé

Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12-connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively.
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hal-04559386 , version 1 (25-04-2024)

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Tim Ahnfeldt, Nathalie Guillou, Daniel Gunzelmann, Irene Margiolaki, Thierry Loiseau, et al.. Al-4(OH)(2)(OCH3)(4)(H2N-bdc)(3)]center dot xH(2)O: A 12-Connected Porous Metal-Organic Framework with an Unprecedented Aluminum-Containing Brick. Angewandte Chemie International Edition, 2009, Angewandte Chemie International Edition, 48, pp.5163-5166. ⟨10.1002/anie.200901409⟩. ⟨hal-04559386⟩
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