Structural, dielectric and magnetic properties of MFeNbO6 materials (M=Ti, Zr, Hf) - Université de Lille
Article Dans Une Revue Solid State Sciences Année : 2024

Structural, dielectric and magnetic properties of MFeNbO6 materials (M=Ti, Zr, Hf)

Résumé

We study the structural, magnetic and electronic properties of MFeNbO6 materials (where A = Ti, Zr or Hf). TiFeNbO6 crystallises with the disordered rutile structure with the P42/mnm space group. Increasing the ionic radii of the M4+ cation going from Ti4+ (0.605 Å) to Zr4+ (0.72 Å) and Hf4+ (0.710 Å) results in a buckling of the octahedral chains with these materials crystallising with the disordered α-PbO2 structure (space group Pbcn). In contrast, with previous reports for TiFeNbO6 we find no evidence of relaxor ferroelectric behaviour with all three materials instead exhibiting Maxwell-Wagner-like relaxation. Impedance spectroscopy confirms semiconductor behaviour. Magnetically, all three materials can be described by infinite irregular antiferromagnetic S = 5/2 chains with weak ferromagnetism below 10 K. These chains have random directions of propagation between nearest Fe–Fe neighbours consistent with the disordered nature of these materials. We observed a negative imaginary part of the ac susceptibility related to the defect magnetic topology.
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Dates et versions

hal-04694809 , version 1 (11-09-2024)

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Elias Djafri, Donna C. Arnold, Angel Arevalo-Lopez, François Fauth, Marielle Huvé, et al.. Structural, dielectric and magnetic properties of MFeNbO6 materials (M=Ti, Zr, Hf). Solid State Sciences, 2024, Solid State Sciences, 154, pp.107581. ⟨10.1016/j.solidstatesciences.2024.107581⟩. ⟨hal-04694809⟩
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